Merge branch 'master' of git+ssh://git@git.eluhost.de:522/qm1-script

This commit is contained in:
Oliver Groß 2008-06-30 15:07:37 +02:00
commit d0db85c772
10 changed files with 354 additions and 26 deletions

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\chapter{Lineare Algebra}
\section{Identitäten}
\begin{math}
A^{-1} = \inlinematrix{a & b \\ c & d}^{-1} = \frac{1}{ad - bc} \inlinematrix{d & -b \\ -c & a}
\end{math}

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\newcommand{\setQ}{\mathbbm{Q}}
\newcommand{\setR}{\mathbbm{R}}
\newcommand{\setC}{\mathbbm{C}}
\newcommand{\einsmatrix}{\mathbbm{1}}
\newcommand{\inlinematrix}[1]{\begin{pmatrix} #1 \end{pmatrix}}
\newcommand{\inlinematrixu}[1]{\begin{matrix} #1 \end{matrix}}
\newcommand{\inlinematrixd}[2]{\left( \begin{matrix} #1\vphantom{#2} \end{matrix} ~\right| \left. \begin{matrix} \vphantom{#1}#2 \end{matrix} \right)}
@ -29,3 +30,8 @@
\newcommand{\diffPfrac}[2]{\frac{\partial #1}{\partial #2}}
\newcommand{\intgr}[4]{\int_{#1}^{#2} #3 ~\text{d}#4}
\newcommand{\intgru}[2]{\int #1 ~\text{d}#2}
\newcommand{\bbracket}[1]{\left #1 \right}
\newcommand{\levicivita}[1]{\varEpsilon_{#1}}
\newcommand{\krondelta}[1]{\delta_{+1}}

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@ -45,6 +45,11 @@
% \include{ueb4}
% \include{ueb5}
% \include{ueb6}
% \inlcude{ueb7}
% \part{Formelsammlung}
% \label{FS}
% \include{formelsammlung}
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\chapter{Quantenmechanik I - Übungsblatt 6}
\section{Aufgabe 14: Spin-1-Teilchen}
\subsection*{a)}
\begin{align}
H &= A S_z + B S_x^2 \\
H &= A \hbar \Sigma_z + B \hbar^2 \Sigma_x^2 \\
H &= A \hbar \inlinematrix{1 &0 &0 \\ 0 &0 &0 \\ 0 &0 &-1} + \frac{B \hbar^2}{2} \inlinematrix{1 &0 &1 \\ 0 &2 &0 \\ 1 &0 &1} \\
H &= \hbar \inlinematrix{A+\frac{B \hbar}{2} &0 &\frac{B \hbar}{2} \\ 0 &\frac{B \hbar}{2} &0 \\ \frac{B \hbar}{2} &0 &-A+\frac{B \hbar}{2}}
\end{align}
$det(H-\lambda \einsmatrix) = 0 \\$
\begin{align}
\lambda_1 &= B\hbar^2 \\
\lambda_2 &= \frac{\hbar^2}{2} B (1 + \sqrt{1 + \frac{4 A^2}{\hbar^2 B^2}} \\
\lambda_3 &= \frac{\hbar^2}{2} B (1-\sqrt{1 + \frac{4 A^2}{\hbar^2 B}}
\end{align}
\begin{align}
a &:= A + \frac{\hbar B}{2} \sqrt{1+\frac{4 A^2}{\hbar^2 B^2}} \\
b &:= \frac{\hbar B}{2} \\
\ket{\phi_0} &= \inlinematrix{0 \\ 1 \\ 0} &
\ket{\phi+} &= \frac{1}{\sqrt{a^2+b^2}} \inlinematrix{a \\ 0 \\ b} &
\ket{\phi-} &= \frac{1}{\sqrt{a^2+b^2}} \inlinematrix{-b \\ 0 \\ a} \\ \\
\ket{\psi(t)} &= c_0 e^{-\i E_0 t} \ket{\phi_0} + c_+ e^{-E_+ t} \ket{\psi_+} + c_- e^{-E_-t t} \ket{\phi-} \\ % muss da nicht e^\i?
\ket{\psi(0)} &= \ket{z+} &= \inlinematrix{1 \\ 0 \\ 0} \\ \\
\end{align}
$\Rightarrow c_0 = 0$
\begin{align}
\frac{1}{\sqrt{a^2+b^2}}(c_+ a - c_- b) &\stackrel{!}{} 1 \\
\frac{1}{\sqrt{a^2+b^2}}(c_+ b + c_- a) &\stackrel{!}{} 0
\end{align}
$\Rightarrow $
\begin{align}
c_- &= \frac{-b\sqrt{a^2+b^2}}{a^2+b^2} \\
c_+ &= \frac{a\sqrt{a^2+b^2}}{a^2+b^2} \\
S_x &= \hbar \Sigma_x &= \hbar \inlinematrix{0 &1 &0 \\ 1 &0 &1 \\ 0 &1 &0}
\end{align}
Da $\inlinematrix{l \\ o \\ m} S_x \inlinematrix{n \\ o \\ p} = 0}$ folgt $S_x = S_y = 0$ %wo kommt das her, und wieso ist hier S_x=0, obwohl es oben != 0 ist
\subsection*{b)}
\begin{align}
S_z &= \hbar \inlinematrix{1 &0 &0 \\ 0 &0 &0 \\ 0 &0 &-1}
\end{align}
\begin{align}
\dirac{\psi(t)}{S_z}{\psi(t)} &= \frac{1}{(a^2+b^2)^2} [(a^2-b^2)^2 + 4a^2b^2cos((E_+-E_-)t)]}
\end{align}
\section{Aufgabe 15: Benzol-Molekül (Teil 2)}
\subsection*{a)}
\begin{align}
P_m H &= \norm{\braket{\phi_m}{\psi(t)}} \\
\ket{\psi(t)} &= U(t,t_0) \ket{\psi(t)} \\ \\
&= exp(-\frac{\i}{\hbar} t H} \\
&= \sum{k=0}{5}{exp(-\frac{\i}{\hbar} t \lambda_k) \ket{\chi_k} \braket{\chi_k}{\phi_0}} \\ %warum 5?
&=^1 \frac{1}{6} \sum{k=0}{5}{\sum{n=0}{5}{exp(-\frac{\i}{\hbar} t (E-2Acos(\delta_k)))}} \\ %warum diese umformung?
P_m(t) &= \norm{\braket{\phi_m}{\psi(t)}} \\
&= \frac{1}{6} \sum{k=0}{5}{\sum{n=0}{5}{exp(...)}\braket{\phi_m}{\phi_n}} \\ %geht die summe wirklich bis 5? und über was?
&=^2 \frac{1}{36} \norm{\sum{k}{biw wo?}{exp(-\frac{\i}{\hbar} t (E-2Acos(\delta_k) + \i \delta_k)}} \\ \\
&= ?
\end{align}
(1)
\begin{align}
\braket{\chi_k}{\phi_0} &= \frac{1}{\sqrt{6}} \sum{n=0}{5}{exp(-\i n \delta_{keine ahnung}\bracket{\phi_n}{\phi_0}} \\ \\
&= \frac{1}{\sqrt{6}} e^{-\i 0 \delta_{keine ahnung}} \\
&= \frac{1}{\sqrt{6}}
\end{align}
(2)
\begin{align}
\braket{\phi_m}{\phi_n} = \delta_{n m}
\end{align}
\subsection*{b)}
\begin{math}
\tau = \frac{2\pi}{A}\hbar
\end{math}
\section{Aufgabe 16: Schrödingergleichung in Impulsraumdarstellung}
\begin{align} \\
%nach schrödingergleichung in ortsdarstellung gucken
\i \hbar \partial_\tau \ket{\psi} &= H \ket{\psi} & \left| \bra{p}\right. \\
\i \hbar \partial_\t \psi(p) &= \dirac{p}{\frac{p^2}{2m}+V(\hat{x}}{\psi}
\end{align}
\begin{align}}
\int_{-\infty}^{\infty} \text{dx} \dirac{p}{V(\hat[x})}{x}\braket{x}{\psi} \\
&= \int_{-\infty}^{\infty} \text{dx} V(x) \frac{1}{\sqrt{2\pi\hbar}}e^{-\frac{\i p}{\hbar}x}\braket{x}{\psi} \\
&= \int_{-\infty}^{\infty} \text{dx} \int_{-\infty}^{\infty} \text{dp'} V(x)\frac{1}{\sqrt{2\pi\hbar}e^{-\frac{\i p}{\hbar}x}\braket{x}{p'}\braket{p'}{x} \\ \\
&= \int_{-\infty}^{\infty}\int_{-\infty}^{\infty} \text{dx} \text{dp'} V(x)\frac{1}{\sqrt{2\pi\hbar}e^{-\frac{i(p-p')}{\hbar}x}\psi(p') \\
&= (2) % aus aufgabenblatt raussuchen
\end{align}
\begin{align}
%wo kommt das her?
\dirac{p}{V(\hat{x}}{\psi} &= \dirac{p}{V(\i\hbar\diffP{p}}{\psi} \\
&= V(\i\hbar\diffP{p})\psi(p) %vertauschen von p und V: Regeln?
\end{align}
\i \hbar

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%\includegraphics{excs/qm1_blatt07_SS08.pdf}
%\pagebreak
\chapter{Quantenmechanik I - Übungsblatt 7}
\section{Aufgabe 17: Unendlich hoher Potentialtop (Ergänzungen)}
\subsection*{a)}
\subsection*{b)}
\subsection*{c)}
\section{Aufgabe 18: Tunneleffekt}
\includegraphics{grafiken/U_A18_1.pdf}
\subsection*{a)}
I
\begin{math}
-\frac{\hbar^2}{2m} \diffPs{x}^2 \Phi(x) = E \Phi(x) \\
\Phi(x) =A e^{\i k x} + B e^{-\i k x} \\
k = \sqrt{\frac{2 E M}{\hbar^2}}
\end{math}
II $E < V_0$
\begin{math}
\Phi(x) = C e^a + D e^{-qx} \\ % ist das nen q hier?
q = \sqrt{\frac{-2m(E-V_0)}{\hbar^2}}
\end{math}
III
\begin{math}
\Phi(x) = \tilde{E} e^{\i k x} + F e^{-\i k x}
\end{math}
\subsection*{b)}
\begin{math}
F = 0
\Phi_I(0) = \Phi_{II}(0) \\
A+B = C+D \\
\diffT{x} \Phi_I(0) = \diffT{x} \Phi_{II}(0) \\ % anschlussbedingungen korrekt
\i k A - \i k B = q C - q D \\
\inlinematrix{1 & 1 \\\i k & -\i k} \inlinematrix{A & B} = \inlinematrix{1 & 1 \\ q & -q} \inlinematrix{C & D} \\
\Phi_{II}(a) = \Phi_{III}(a) \\
C e^{a \cdot a} + D e^{-a \cdot a} = \tilde{E} e^{\i k a} \\
\diffT{x} \Phi_{II}(a) = \diffT{x} \Phi_{III}(a) \\
q C e^{a \cdot a} - q D e^{-a \cdot a} = \i k \tilde{E} e^{\i k a} \
\inlinematrix{e^{a \cdot a} & e^{-a \cdot a} \\ q e^{a \cdot a} & q e^{-a \cdot a}} \inlinematrix{C & D} = \inlinematrix{\tilde{E} e^{\i k a} \\ \i k \tilde{E} e^{\i k a}}
\end{math}
mit den Inversen von: (1) und (2) % geschweifte klammern unter matrix 1 und 2 setzen
\begin{math}
%mit maxima berechnet
\inlinematrix{C & D} = \inlinematrix{\frac{{e}^{{a}^{2}}}{{e}^{2 {a}^{2}}-1} & -\frac{1}{\left( {e}^{3\,{a}^{2}}-{e}^{{a}^{2}}\right) q} \\ -\frac{{e}^{{a}^{2}}}{{e}^{2{a}^{2}}-1} & \frac{{e}^{{a}^{2}}}{\left( {e}^{2 {a}^{2}}-1\right) q}} \inlinematrix{\tilde{E} e^{\i k a} \\ \i k \tilde{E} e^{\i k a}} \\
\inlinematrix{A & B} = \inlinematrix{\frac{1}{2} & -\frac{\i}{2k}\\ \frac{1}{2} & \frac{\i}{2k}} \inlinematrix{1 & 1 \\ q & -q} \inlinematrix{C & D}
\end{math}
$\inlinematrix{C & D}$ eingesetzt ergibt:
\begin{align}
\tilde{E} &= \frac{2 k a}{e^{ika} \bbracket{(q^2 - k^2) \cdot \i sinh(q \cdot a) - 2 k q cosh(qa)} \\
A &= 1 \\
T &= \bbracket{\frac{E}{A}}^2 \\
R &= 1 - T &= \bbracket{\frac{B}{A}}^2 \\
T &= \frac{1}{\bbracket{\frac{a^2 - k^2}{2 q k}} \cdot 2 sinh^2(q a) + cosh^2(q a)}
\end{align}
\subsection*{c)}
\section{Aufgabe 19: Doppeltes \delta-Potential}
\subsection*{a)}
\subsection*{b)}
\subsection*{c)}
\subsection*{d)}